Fe和Co离子在YBCO中团簇效应的理论和实验研究

通过数值模拟计算和正电子湮没等方法,系统研究了磁性离子Fe和Co掺杂的YBCO系列样品,结果表明,小掺杂量时离子以分散形式存在,随着掺杂量增大,离子以不同的团簇形式进入晶格,并通过团簇带入氧离子.在Cu-O链区域六离子团簇出现的几率最大,团簇效应抑制了空穴载流子的产生及其向CuO2面区域的转移,弱化了载流子库的功能.然而由于它们仅间接影响了电子的配对和输运,因而对超导电性抑制较弱.另外,通过与非磁性离子掺杂效应等因素比较,显示出Fe和Co掺杂对超导电性抑制与其磁性没有直接关联.     

利用专家经验对活动断裂进行量化的模糊数学模型

本模型可以根据专家对部分活动断裂的评定,用模糊数学中的信息扩散原理和随机集落影方法,提取活动断裂在评定中的量化指标,让专家经验更好地被一般考察人员所掌握,便于提供大量的活动断裂信息,为分析活动断裂对震害的定量影响创造条件.     

A stochastic discrete model of tissue and its ultrasonic backscattering coefficient

TheprojectissupportedbyNationalNaturalScienceFoundationofChina.I.IntroductionU1trasonicpropagationandscatteringinthebiologica1softtissuesisabasicprob-lemofbiomedica1u1trasonics,andu1trasonicbackscatteringfromthetissucsproduccs..importantinformationfortissuecharacterizationaswe11asfortissueimagind'.2].Tissuemodellingisfundamentalfortheanalysisofultrasonicbackscattering.Vari-ousmode1shavebeensuggestedwithapartialsuccess.Sofar,therearetwomajortypesofmodc1s,theinhomogeneouscontinuummode1andthed…     

Production and characterization of monoclonal antibody for class-specific determination of O,O-dimethyl organophosphorus pesticides and effect of heterologous coating antigens on immunoassay sensitivity

A generic hapten (H1), 3-(4-Dimethoxyphosphorothioyloxy phenyl)propanoic acid, was synthesized to produce monoclonal antibodies (mAbs) for the determination of organophosphorus pesticides (OPs) in a class-specific manner. Six heterologous haptens were designed to study the effect of hapten heterology on immunoassay sensitivity. Several mice were immunized with this H1-BSA immunogen. Spleen cells of two immunized mice were fused with myeloma cells, and the resulting hybridomas were screened using H1-OVA. In a competitive indirect enzyme-linked immunosorbent assay (ELISA) format, three hybridoma cell lines (B4-C6, D12-B5, E5-H2) that produced mAbs with high selectivity and broad specificity were selected and expanded. The monoclonal antibody D12-B5 with higher titer was chosen for further study. In heterologous assay, the combination of D12-B5 and coating antigen H7-OVA constituted a particularly sensitive assay for competitive indirect ELISA and showed broad specificity for the determination of OPs, including parathion-methyl, chlorpyrifos-methyl, tolclofos-methyl, fenthion, malathion, fenitrothion. This combination resulted in the IC₅₀ of 0.58-10.47 µg/ml.     

Ab initio study of the potential energy surface and product branching ratios for the reaction of O(D) with CH3CH2F

The potential energy surface of O(¹D) + CH₃CH₂F reaction has been studied using QCISD(T)/6-311++G(d,p)//MP2/6-311G(d,p) method. The calculations reveal an insertion–elimination reaction mechanism of the title reaction. The insertion process has two possibilities: one is the O(¹D) atom inserting into C–F bond of CH₃CH₂F produces one energy-rich intermediate CH₃CH₂OF and another is the O(¹D) atom inserting into one of the C–H bonds of CH₃CH₂F produces two energy-rich intermediates, IM1 and IM2. The three intermediates subsequently decompose to various products. The calculations of the branching ratios of various products formed though the three intermediates have been carried out using RRKM theory at the collision energies of 0, 5, 10, 15, 20, 25 and 30 kcal/mol. CH₃CH₂O is the main decomposition product of CH₃CH₂OF. HF and CH₃ are the main decomposition products for IM1; CH₂OH is the main decomposition product for IM2. Since IM1 is more stable and more likely to form than CH₃CH₂OF and IM2, HF and CH₃ are probably the main products of the O(¹D) + CH₃CH₂F reaction. Our computational results can give insight to reaction mechanism and provide probable explanations for future experiments.     

YBCO薄膜过电流失超特性实验及分析

YBCO薄膜材料作为电阻型高温超导限流器的限流元件具有单位通流长度耐压高,失超后不易损毁等优点.本文设计一套实验设备,在不同幅值交流电源条件下,对YBCO薄膜过电流失超特性进行了测量.实验得到了在不同过电流作用下YBCO薄膜的阻抗及电压随时间的变化关系.大量实验数据表明,YBCO对短路电流有很好的限流效果.并且动作迅速,失超后有效限流电阻大.结合实验数据,文中将YBCO薄膜的过电流失超过程分为三个不同阶段.对应于不同幅值的交流电源,分析了不同阶段YBCO的电阻发展过程.本文得到的结论对YBCO薄膜限流元件的建模及失超传播分析有着重要的参考意义.     

Scattering of guided SH-wave by a partly debonded circular cylinder in a traction free plate

A solution of the scattering problem of guided SH-wave by a partly debonded circular cylinder centered in a traction free plate has been set up. The plate is divided up into three regions with two imaginary planes perpendicular to the plate walls. In the central region where the partly debonded cylindrical obstacle is posted, the wave field is expanded into the cylindrical wave modes and Chebyshev polynomials. In the other two exterior regions the fields are expanded into the plate wave modes. A system of fundamental equations to solve the problem is obtained according to the traction free boundary condition on the plate walls and the continuity condition of the traction and the displacement across the imaginary planes. The approximate numerical method termed mode-matching technique is used to construct a matrix equation to obtain curves showing the coefficient of reflection and transmission versus the ratio of the cylinder’s radius to the plate’s half-thickness and the angular width of the debonded region. A comparison of the numerical results between the welded interface condition and the debonded interface condition is made, and the results are discussed.     

Tame 遗传代数导出的 Lie代数

设A是有限域k上的有限维tame遗传代数,X,Y,M是有限生成A模,如果X,Y不可分解,证明了存在Hall多项式gMXY.设L(A)是以有限生成不可分解模为基的自由Abel群,则L(A)是退化Ringel-Hall代数(A)1的Lie子代数,设L′(A)是L(A)的由单模生成的Lie子代数,m是齐次正则单模的长度,证明了当M不可分解且m不整除M的长度时,［M］∈L′(A).     

A位Eu掺杂对La0.7Ca0.3MnO3电输运的影响

采用传统的固相反应法制备出了高质量的La_(0.7)Ca_(0.3)MnO_3(其中x=0.00,0.05,0.10,0.15,0.20)系列样品,并对其进行了XRD,电阻-温度测量.实验结果表明,随着Eu掺杂量的增加,样品的金属-绝缘体转变温度朝低温附近移动,峰值电阻增加.通过对A位平均离子半径和尺寸无序度的计算,我们发现,由Eu掺杂导致A位平均离子半径〈rA〉减小,尺寸无序度σ2增大,使晶格畸变加剧,从而削弱了eg巡游电子在Mn3 和Mn4 之间的跃迁,同时促进了自旋极化子的形成.我们还对样品电阻-温度曲线的高温部分进行了拟合,对于x=0.00的样品,曲线可以用非绝热近似下的小极化子模型拟合;当掺杂量为x=0.05,0.10,样品的导电机理符合变程跳跃模型;进一步加大掺杂量,当x=0.15,0.20时,样品的电输运行为可以用晶格极化子与自旋极化子共存来解释.